I find that a lot of stuff that I read is mislabeled paranormal romance, because it's urban fantasy with more or less a romantic subplot. My favorites in this genre are all of Carrie Vaughn's books, starting with Kitty and the Midnight Hour, Kim Harrison's Dead Witch Walking (which has no romantic element really, but hints to later books which I haven't read), and Kelley Armstrong's Bitten, which is VERY MUCH paranormal romance.

I've read a few of Asaro's Skolian Empire books and have enjoyed them, but I can't think of other writers, off the top of my head, that write SFR.

But Juno Books's anthology, Best New Paranormal Romance had some good stories in it, and introduced me to Sandra McDonald, whose SF (with a romantic subplot?) novel, The Outback Stars debuted earlier this year. I've got it, but haven't read it yet.

Alas. So many books, so little time...